Seconding @FindingLibido good on you for having a go and trying something new.
That being said, prep is definitely key for you both to get fun out of it.
Google anal training. Get yourself some butt plugs and a decent quality anal lube (sliquid sassy is my go to for anal and its silicon compatible)
This is going to be particularly important if she wants to try with a decent sized dildo (length is one of the dimensions that define how intense a toy will feel when in)
Start with your fingers or a small plug. 3.5inch circumference is a good starting point size wise. (This one is a good option. Or the rocks off one if you want to start even smaller)
Anal play will feel odd to begin with as its a new sensation your brain wont know how to process. So dont be put off. If your doing it right it shouldn’t hurt though, so if it feels uncomfortable (or you get butt cramp) take it out.
There is a ton of advice on using plugs and anal dildos on here if you search the forum
Do have a look for a longer version of this.
Wash up and go to the loo before doing anal play.
Lube up around and inside using your fingers. Lube the toy too. Lube is really crucial so dont be scared to take it out and reapply lube to a toy if you feel you need to. Wetter is definitely better
Always pick anal safe toys with a wide base for this kind of play. Really important
Body safe materials are best too for anything anal (eg. Silicone, glass, metal)
Stick with silicone for your first plug. The others are more intense
When your inserting something make sure to take long deep breaths and relax. (I find concentrating on how much you want a toy in and how good it will feel helps too). Go slow, listen to your body. Teasing a toy in and out slightly and using the vibes (if the toys got them) around your rim can also help relax everything down there when you insert stuff.
If you feel yourself tensing up on a toy thats in just make sure to take deep breaths and relax.
Once you can use a plug comfortably go up a size (plus one inch circumference between toys is max. 0.5 is what i did as i found it more comfy). Work up to a size slightly larger than whatever dildo you pick. (This will take a few weeks min so dont rush it)
Make sure to use the dildo solo before she peggs you with is so you can go slow and adjust to it.
Using a dildo anally isharder on the muscles than a plug so taking your time is really important.
Hopefully this should make it all much more fun for you both (apologies, i know that was rather long)
Oh, you can also wear a plug before she peggs you, or you use a dildo. good way to stretch